Reply to Objection 3. Names are given to things considered in reference to their end and state of completeness. Now a disposition is not an end, whereas perfection is. Consequently things that signify disposition to holiness are not called sacraments, and with regard to these the objection is verified: only those are called sacraments which signify the perfection of holiness in man.Thomas Aquinas. Summa theological, III, q.60, in First Complete American Edition in Three Volumes. Vol. 2. Trans. Fathers of the English Dominican Province. (New York,NY: Benziger, 1947), #’s.
In the process of distinguishing sacraments he kind of accidentally defines sacramentals without addressing them directly, and guess what, the distinction is made upon that which disposes and that which perfects and actualizes. This fits in great with what I've been thinking is the primary significance of sacramentals and thus blessings, that by them we may really be disposed, by an operation of grace which disposes, in other words, actual grace.